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Preparation of lithium ion-sieve and utilizing in recovery of lithium from seawater

Lu WANG, Changgong MENG, Wei MA

《化学科学与工程前沿（英文）》 2009年 第3卷 第1期   页码 65-67 doi: 10.1007/s11705-009-0105-9

摘要： Lithium is one of the most important light metals, which is widely used as raw materials for large-capacity rechargeable batteries, light aircraft alloys and nuclear fusion fuel. Seawater, which contains 250 billion tons of lithium in total, has thus recently been noticed as a possible resource of lithium. While, since the average concentration of lithium in seawater is quite low (0.17 mg·L ), enriching it to an adequate high density becomes the primary step for industrial applications. The adsorption method is the most prospective technology for increasing the concentration of lithium in liquid. Among the adsorbents for lithium, the ion-sieve is a kind of special absorbent which has high selectivity for Li , especially the spinel manganese oxides (SMO), which among the series of ion-sieves, has become the most promising adsorption material for lithium. In this study, the SMO ion-sieve was prepared by a coprecipitation method. The preparation conditions were discussed and the sample characters were analyzed. Recovery of Li from seawater were studied in batch experiments using prepared ion-sieve, and the effect of solution pH and the uptake rates were also investigated in different Li solutions.

关键词： lithium     ion-sieve     seawater     spinel manganese oxide    

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Preparation and characterization of novel carbon molecular sieve membrane/PSSF composite by pyrolysis

Ying Yan, Peng Huang, Huiping Zhang

《化学科学与工程前沿（英文）》 2019年 第13卷 第4期   页码 772-783 doi: 10.1007/s11705-019-1827-y

摘要： Carbon molecular sieve membrane (CMSM)/paper-like stainless steel fibers (PSSF) has been manufactured by pyrolyzing poly (furfuryl alcohol) (PFA) coated on the metal fibers. PFA was synthesized using oxalic acid dihydrate as a catalyst and coated on microfibers by dip coating method. For the purpose of investigating the effects of final carbonization temperature, the composites were carbonized between 400°C and 800°C under flowing nitrogen. The morphology and microstructure were examined by X-ray diffraction, Fourier transforms infrared spectroscopy, scanning electron microscopy, thermogravimetric analysis, N adsorption and desorption, Raman spectra and X-ray photoelectron spectra. The consequences of characterization showed that the CMSM containing mesopores of 3.9 nm were manufactured. The specific surface area of the CMSM/PSSF fabricated in different pyrolysis temperature varies from 26.5 to 169.1 m ∙g and pore volume varies from 0.06 to 0.23 cm ∙g . When pyrolysis temperature exceeds 600°C, the specific surface, pore diameter and pore volume decreased as carbonization temperature increased. Besides, the degree of graphitization in carbon matrix increased with rising pyrolysis temperature. Toluene adsorption experiments on different structured fixed bed that was padded by CMSM/PSSF and granular activated carbon (GAC) were conducted. For the sake of comparison, adsorption test was also performed on fixed bed packed with GAC. The experimental results indicated that the rate constant ′ was dramatically increased as the proportion of CMCM/PSSF composites increased on the basis of Yoon-Nelson model, which suggested that structured fixed bed padded with CMSM/PSSF composite offered higher adsorption rate and mass transfer efficiency.

关键词： carbon molecular sieve membrane     stainless steel fibers     pyrolysis     structured fixed bed     toluene    

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Thermal decomposition of poly(ethylene terephthalate)/mesoporous molecular sieve composites

RUN Mingtao, ZHANG Dayu, WU Sizhu, WU Gang

《化学科学与工程前沿（英文）》 2007年 第1卷 第1期   页码 50-54 doi: 10.1007/s11705-007-0010-z

摘要： The nonisothermal and isothermal degradation processes of poly (ethylene terephthalate)/mesoporous molecular sieve (PET/MMS) composites synthesized by in-situ polymerization were studied by using thermogravimetric analysis in nitrogen. The nonisothermal degradation of the composite is found to be the first-order reaction. An iso-conversional procedure developed by Ozawa is used to calculate the apparent activation energy (), which is an average value of about 260 kJ/mol with the weight conversion from 0% to 30%, and is higher than that of neat PET. Isothermal degradation results are confirmed with the nonisothermal process, in which PET/MMS showed higher thermal stability than neat PET. The polymer in mesoporous channels has more stability due to the protection of the inorganic pore-wall. These results indicate that mesoporous MMS in PET/MMS composites improve the stability of the polymer.

关键词： polymerization     isothermal degradation     conversion     nonisothermal degradation     activation    

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Energy absorption potential of concrete floors containing secondary (shrinkage and temperature) reinforcements

K. S. SIVAKUMARAN,R. M. KOROL,Xiao FAN

《结构与土木工程前沿（英文）》 2014年 第8卷 第3期   页码 282-291 doi: 10.1007/s11709-014-0269-3

摘要： This paper experimentally investigates the energy absorption potential of two types of concrete floors, namely, normal density concrete and structural low-density concrete, containing secondary (shrinkage and temperature) reinforcements. The test program considered the following secondary reinforcements: 1) traditional welded-wire steel mesh, 2) steel fiber and 3) poly composite fiber. To estimate the extent to which crushing of floor slab materials would help absorb energy, a series of concrete penetration tests employing patch loading was undertaken on scaled down model slabs. Each concrete-secondary reinforcement combination considered slabs of 50 mm in depth with square plan dimensions ranging from 50 to 500 mm, resulting in a total of 30 test specimens. The first part of the paper discusses the test specimens, the test setup, and the test procedure. The second part of the paper presents the experimental results and establishes the energy absorption of different concrete- secondary reinforcement combinations. Sieve analysis results of the crushed specimens were used to derive a “work index” value that relates the pulverized particle size distributions to energy inputs. The work index values of concrete-secondary reinforcement systems can be used to assess the energy dissipation potential associated with such floor slabs in buildings undergoing progressive collapse. The results indicate that floors with secondary reinforcements could play an important role in helping arrest global progressive collapse.

关键词： concrete floors     structural low-density concrete     shrinkage and temperature reinforcements     energy absorption     penetration tests     sieve analysis    

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Preparation and characterization of lithium

Chang WANG,Yanlong ZHAI,Xi WANG,Ming ZENG

《化学科学与工程前沿（英文）》 2014年 第8卷 第4期   页码 471-477 doi: 10.1007/s11705-014-1449-3

摘要： Lithium -MnO ion-sieves were prepared from spinel LiMn O via treatment with nitric acid. The LiMn O was synthesized by a solid state reaction between LiOH·H O and MnO . The effects of the calcination time and temperature on the preparation of the LiMn O precursor and the lithium ion-sieve were investigated. In addition, the Li extraction ratio, the Mn dissolving ratio and the adsorption properties of the lithium ion-sieve were all measured. The lithium ion-sieve had a high exchange capacity and was selective for Li . Specifically, at pH= 13, the ion exchange capacity of Li was 30.9 mg/g in 10 mmol/L LiCl solution and the lithium extraction ratio and manganese dissolving ratio were 95% and 25%, respectively.

关键词： lithium ion-sieve     solid state reaction     adsorption     LiMn2O4    

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Ti incorporation in MCM-41 mesoporous molecular sieves using hydrothermal synthesis

Shengping WANG, Changqing MA, Yun SHI, Xinbin MA

《化学科学与工程前沿（英文）》 2014年 第8卷 第1期   页码 95-103 doi: 10.1007/s11705-014-1405-2

摘要： Titanium-containing mesoporous materials (Ti-MCM-41) were obtained by hydrothermal synthesis. Such materials are active catalysts for the transesterification of dimethyl oxalate and phenol to produce diphenyl oxalate. To understand the role of the Ti in the catalytic process, Ti-MCM-41 samples with different Si/Ti ratios (from 5 to 100) were prepared and the samples were analyzed by Fourier transform infrared spectroscopy, UV-visible spectroscopy, and ammonia temperature programmed desorption. It was concluded that the Ti is incorporated into the framework of the MCM-41 and formed weak Lewis acid sites. In addition, the number of Ti(IV) sites increased as the amount of titanium increased. X-ray powder diffraction, N adsorption-desorption and transmission electron microscopy results showed that the Ti-MCM-41 samples have a hexagonal arrangement of mono-dimensional pores. A large number of Ti(IV) sites coupled with the mesoporous structure and large pore diameters are favorable for the transesterification catalytic properties of Ti-MCM-41.

关键词： Ti-MCM-41     mesoporous molecular sieve     acid sites     transesterification     hydrothermal synthesis    

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Oxidation-extraction desulfurization of model oil over Zr-ZSM-5/SBA-15 and kinetic study

Chuanzhu LU,Hui FU,Huipeng LI,Hua ZHAO,Tianfeng CAI

《化学科学与工程前沿（英文）》 2014年 第8卷 第2期   页码 203-211 doi: 10.1007/s11705-014-1420-3

摘要： ZSM-5/SBA-15 composite molecular sieves were synthesized using post-synthesis method and characterized by X-ray diffraction and N adsorption-desorption. The oxidative-extration desulfurization of model oil was investigated by using hydrogen peroxide as the oxidant, tetrabutyl ammonium bromide as phase transfer catalyst, dimethyl sulfoxide as extractant, and Zr-ZSM-5/SBA-15, Ag-ZSM-5/SBA-15, Ce-ZSM-5/SBA-15 as catalyst. Under the optimal conditions, the desulfurization rate decreases in the order: Zr-ZSM-5/SBA-15>Ce-ZSM-5/SBA-15>Ag-ZSM-5/SBA-15. The highest desulfurization rate is 84.53% under the catalysis of Zr-ZSM-5/SBA-15. Kinetics analysis shows that the reaction is pseudo-first-order with the activation energy of 44.23 kJ/mol.

关键词： composite molecular sieve     oxidation desulfuration     extraction     kinetic    

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Catalytic oxidation of carbon monoxide, toluene, and ethyl acetate over the

Zhidan Fu, Lisha Liu, Yong Song, Qing Ye, Shuiyuan Cheng, Tianfang Kang, Hongxing Dai

《化学科学与工程前沿（英文）》 2017年 第11卷 第2期   页码 185-196 doi: 10.1007/s11705-017-1631-5

摘要： The Pd catalyst supported on cryptomelane-type manganese oxide octahedral molecular sieve (OMS-2) were prepared. The effect of Pd loading on the catalytic oxidation of carbon monoxide, toluene, and ethyl acetate over Pd/OMS-2 has been investigated. The results show that the Pd loading plays an important role on the physicochemical properties of the Pd/OMS-2 catalysts which outperform the Pd-free counterpart with the 0.5Pd/OMS-2 catalyst being the best. The temperature for 50% conversion was 25, 240 and 160 °C, and the temperature for 90% conversion was 55, 285 and 200 °C for oxidation of CO, toluene, and ethyl acetate, respectively. The low-temperature reducibility and high oxygen mobility of Pd/OMS-2 are the factors contributable to the excellent catalytic performance of 0.5Pd/OMS-2.

关键词： cryptomelane-type manganese oxide octahedral molecular sieve     oxygen mobility     reducibility     carbon monoxide oxidation     volatile organic compound combustion    

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The synergic effects of highly selective bimetallic Pt-Pd/SAPO-41 catalysts for the

Guozhi Jia, Chunmu Guo, Wei Wang, Xuefeng Bai, Xiaomeng Wei, Xiaofang Su, Tong Li, Linfei Xiao, Wei Wu

《化学科学与工程前沿（英文）》 2021年 第15卷 第5期   页码 1111-1124 doi: 10.1007/s11705-020-2031-9

摘要： The hydroisomerization of -hexadecane over Pt-Pd bimetallic catalysts is an effective way to produce clean fuel oil. This work reports a useful preparation method of bimetallic bifunctional catalysts by a co-impregnation or sequential impregnation process. Furthermore, monometallic catalysts with loading either Pt or Pd are also prepared for comparison. The effects of the metal species and impregnation order on the characteristics and catalytic performance of the catalysts are investigated. The catalytic test results indicate that the maximum -hexadecane yield over different catalysts increases as follows: Pt/silicoaluminophosphate SAPO-41

关键词： SAPO-41 molecular sieve     Pt-Pd bimetallic site     bifunctional catalysts     n-hexadecane     hydroisomerization    

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15th International Congress for Stereology and Image Analysis 第十五届国际体视学与图像分析学术会议

会议日期： 2019年05月27日

会议地点： 丹麦/奥胡斯

主办单位： 国际体视学与图像分析学会(ISSIA)

Decomposition analysis applied to energy and emissions: A literature review

《工程管理前沿（英文）》   页码 625-639 doi: 10.1007/s42524-023-0270-4

摘要： Decomposition analysis has been widely used to assess the determinants of energy and CO2 emissions in academic research and policy studies. Both the methodology and application of decomposition analysis have been largely improved in the past decades. After more than 50 years’ developments, decomposition studies have become increasingly sophisticated and diversified, and tend to converge internally and integrate with other analytical approaches externally. A good understanding of the literature and state of the art is critical to identify knowledge gaps and formulate future research agenda. To this end, this study presents a literature survey for decomposition analysis applied to energy and emission issues, with a focus on the period of 2016–2021. A review for three individual decomposition techniques is first conducted, followed by a synthesis of emerging trends and features for the decomposition analysis literature as a whole. The findings are expected to direct future research in decomposition analysis.

关键词： index decomposition analysis     structural decomposition analysis     production decomposition analysis     energy     CO2 emissions    

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Flow, thermal, and vibration analysis using three dimensional finite element analysis for a flux reversal

B. VIDHYA,K. N. SRINIVAS

《能源前沿（英文）》 2016年 第10卷 第4期   页码 424-440 doi: 10.1007/s11708-016-0423-9

摘要： This paper presents the simulation of major mechanical properties of a flux reversal generator (FRG) viz., computational fluid dynamic (CFD), thermal, and vibration. A three-dimensional finite element analysis (FEA) based CFD technique for finding the spread of pressure and air velocity in air regions of the FRG is described. The results of CFD are mainly obtained to fine tune the thermal analysis. Thus, in this focus, a flow analysis assisted thermal analysis is presented to predict the steady state temperature distribution inside FRG. The heat transfer coefficient of all the heat producing inner walls of the machine are evaluated from CFD analysis, which forms the main factor for the prediction of accurate heat distribution. The vibration analysis is illustrated. Major vibration sources such as mechanical, magnetic and applied loads are covered elaborately which consists of a 3D modal analysis to find the natural frequency of FRG, a 3D static stress analysis to predict the deformation of the stator, rotor and shaft for different speeds, and an unbalanced rotor harmonic analysis to find eccentricity of rotor to make sure that the vibration of the rotor is within the acceptable limits. Harmonic analysis such as sine sweep analysis to identify the range of speeds causing high vibrations and steady state vibration at a mode frequency of 1500 Hz is presented. The vibration analysis investigates the vibration of the FRG as a whole, which forms the contribution of this paper in the FRG literature.

关键词： flux reversal generator     air velocity     computation fluid dynamics     thermal analysis     vibration analysis     finite element analysis    

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Review of sentiment analysis: An emotional product development view

《工程管理前沿（英文）》   页码 592-609 doi: 10.1007/s42524-022-0227-z

摘要： Conveying consumers’ specific emotions in new products, referred to as emotional product development or emotional design, is strategically crucial for manufacturers. Given that sentiment analysis (SA) can extract and analyze people’s opinions, sentiments, attitudes, and perceptions regarding different products/services, SA-based emotional design may provide manufacturers with real-time, direct, and rapid decision support. Despite its considerable advancements and numerous survey and review articles, SA is seldom considered in emotional design. This study is among the first efforts to conduct a thorough review of SA from the view of emotional design. The comprehensive review of aspect-level SA reveals the following: 1) All studies focus on extracting product features by mixing technical product features and consumers’ emotional perceptions. Consequently, such studies cannot capture the relationships between technical and emotional attributes and thus cannot convey specific emotions to the new products. 2) Most studies use the English language in SA, but other languages have recently received more interest in SA. Furthermore, after conceptualizing emotion as Kansei and introducing emotional product development and Kansei Engineering, a review of the data-driven emotional design is then conducted. A few efforts start to study emotional design with the help of SA. However, these studies only focus on either analyzing consumers’ preferences on product features or extracting emotional opinions from online reviews, thus cannot realize data-driven emotional product development. Finally, some research opportunities are provided. This study opens a broad door to aspect-level SA and its integration with emotional product development.

关键词： sentiment analysis     emotion     product development     Kansei Engineering    

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标题 作者 时间 类型 操作

Preparation of lithium ion-sieve and utilizing in recovery of lithium from seawater

Lu WANG, Changgong MENG, Wei MA

期刊论文

Preparation and characterization of novel carbon molecular sieve membrane/PSSF composite by pyrolysis

Ying Yan, Peng Huang, Huiping Zhang

期刊论文

Thermal decomposition of poly(ethylene terephthalate)/mesoporous molecular sieve composites

RUN Mingtao, ZHANG Dayu, WU Sizhu, WU Gang

期刊论文

Energy absorption potential of concrete floors containing secondary (shrinkage and temperature) reinforcements

K. S. SIVAKUMARAN,R. M. KOROL,Xiao FAN

期刊论文

Preparation and characterization of lithium

Chang WANG,Yanlong ZHAI,Xi WANG,Ming ZENG

期刊论文

Ti incorporation in MCM-41 mesoporous molecular sieves using hydrothermal synthesis

Shengping WANG, Changqing MA, Yun SHI, Xinbin MA

期刊论文

Oxidation-extraction desulfurization of model oil over Zr-ZSM-5/SBA-15 and kinetic study

Chuanzhu LU,Hui FU,Huipeng LI,Hua ZHAO,Tianfeng CAI

期刊论文

Catalytic oxidation of carbon monoxide, toluene, and ethyl acetate over the

Zhidan Fu, Lisha Liu, Yong Song, Qing Ye, Shuiyuan Cheng, Tianfang Kang, Hongxing Dai

期刊论文

The synergic effects of highly selective bimetallic Pt-Pd/SAPO-41 catalysts for the

Guozhi Jia, Chunmu Guo, Wei Wang, Xuefeng Bai, Xiaomeng Wei, Xiaofang Su, Tong Li, Linfei Xiao, Wei Wu

期刊论文

15th International Congress for Stereology and Image Analysis 第十五届国际体视学与图像分析学术会议

2019年05月27日

会议信息

黄幼麟：Dynamic Consumer Preferences for Electric Vehicles — A Longitudinal Analysis（2020年7月12日）

2022年06月10日

会议视频

福田敏男：Bio Cell Analysis and Assembly by Micro and Nano Robotic Technology（2019年8月25日）

福田敏男(院士)

2021年01月20日

会议视频

Decomposition analysis applied to energy and emissions: A literature review

期刊论文

Flow, thermal, and vibration analysis using three dimensional finite element analysis for a flux reversal

B. VIDHYA,K. N. SRINIVAS

期刊论文

Review of sentiment analysis: An emotional product development view

期刊论文